| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10578814 | Polyhedron | 2005 | 6 Pages |
Abstract
Reaction of TiCl4 with the reagents RN(SiMe3)2 in dichloromethane precipitates red to black powders (R = 1-adamantyl, phenyl, pentafluorophenyl, 3,5-bis(trifluoromethyl)phenyl), which on treatment with tetrahydrofuran give the new THF adducts [Ti(NR)Cl(μ-Cl)(THF)2]2.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and catalytic activity of dinuclear imido titanium complexes: the molecular structure of [Ti(NPh)Cl(μ-Cl)(THF)2]2](/preview/png/10578814.png "First Page Preview: Synthesis and catalytic activity of dinuclear imido titanium complexes: the molecular structure of [Ti(NPh)Cl(μ-Cl)(THF)2]2")
Authors
Dale A. Pennington, Peter N. Horton, Michael B. Hursthouse, Manfred Bochmann, Simon J. Lancaster,