Article ID Journal Published Year Pages File Type
10610241 Journal of Molecular Structure 2005 6 Pages PDF
Abstract
A novel metal-organic coordination polymer, [Cd(HPT)2(4,4′-bpy)]n (PT=phthalate), has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Colorless crystals crystallized in the tetragonal system, space group I4122, a=8.294(5), b=8.294(5), c=33.7535(17) Å, V=2321.8(18) Å3, Z=4 and R=0.0207. The structure of the compound exhibiting a homochiral 3D covalent framework based on achiral bridging ligands has been constructed by an alternating assembly of vertical chiral layers consisting of homochiral helices.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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