Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10610241 | Journal of Molecular Structure | 2005 | 6 Pages |
Abstract
A novel metal-organic coordination polymer, [Cd(HPT)2(4,4â²-bpy)]n (PT=phthalate), has been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Colorless crystals crystallized in the tetragonal system, space group I4122, a=8.294(5), b=8.294(5), c=33.7535(17)Â Ã
, V=2321.8(18)Â Ã
3, Z=4 and R=0.0207. The structure of the compound exhibiting a homochiral 3D covalent framework based on achiral bridging ligands has been constructed by an alternating assembly of vertical chiral layers consisting of homochiral helices.
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Authors
Xinlong Wang, Chao Qin, Enbo Wang, Lin Xu,