Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10610242 | Journal of Molecular Structure | 2005 | 5 Pages |
Abstract
A novel Ag(I) coordination polymer, [Ag2(μ-ptmb)(μ3-ptmb)]·2H2O (1), (ptmb=4-(4-pyridylthiomethyl)benzoate), has been synthesized through self-assembly of AgNO3 with Hptmb in CH3CN/H2O mixed solution and characterized by elemental analysis and IR spectra. X-ray diffraction analysis shows that it is a 1D tape-like structure consisting of two kinds of rectangles, which is further hierarchically assembled by Agâ¯S and Sâ¯S weak interactions to form 3D open framework. Luminescence study indicates the complex has an emissive maximum at 500 nm in the solid state at room temperature.
Related Topics
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Authors
Lei Han, Ruihu Wang, Daqiang Yuan, Benlai Wu, Benyong Lou, Maochun Hong,