| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10631187 | Journal of Non-Crystalline Solids | 2011 | 6 Pages |
Abstract
⺠At high temperatures, redox reactions in glass melts are in equilibrium. ⺠Around the glass transition temperature the reaction between chromium and manganese species is controlled by the kinetics. ⺠At lower temperatures, the reaction is frozen. ⺠These freezing temperatures depend on the cooling rate similar to Bartenev equation. ⺠The rate determining step in this case is the electron transfer, because a notable structural rearrangement is necessary.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Ladislav Kido, Matthias Müller, Isak Avramov, Christian Rüssel,