Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10631195 | Journal of Non-Crystalline Solids | 2011 | 4 Pages |
Abstract
⺠Little change in the local structure of a-(Ni0.6Nb0.4)65Zr35 was shown after 7.8at% H2 charge. ⺠Ab initio calculation indicates Ni-centered Ni5Nb3Zr5 icosahedron is the most stable cluster. ⺠XAFS results of Ni K-edge can be well represented by distorted Ni-centered Ni5Nb3Zr5 cluster. ⺠A large tetrahedron in this cluster can trap hydrogen without changing in the local structure.
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Authors
M. Matsuura, M. Fukuhara, K. Konno, T. Fujita, M.W. Chen, N. Fujima, A. Inoue,