Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10706552 | Current Applied Physics | 2005 | 4 Pages |
Abstract
The preparation and photophysics of organometallic Ir(III) complexes with 3-phenylpyridazine (H6Clppdz) and its derivative are reported. IrCl3 · nH2O reacts with H6Clppdz, and 3-chloro-6-(3â²-methoxyphenyl)-4-methyl-pyridazine (MCOMppdz) to give the corresponding chloride-bridged dimers, (6Clppdz)2Ir(μ-Cl)2Ir(6Clppdz)2 and (MCOMppdz)2Ir(μ-Cl)2Ir(MCOMppdz)2 in good yields. These chloride-bridged dimers are cleaved with 2-pyrazinecarboxylic acid (Hpyzc), 2-picolinic acid (Hpic), acetylacetone (Hacac), and 2,2,6,6-tetramethyl-3,5-heptanedione (Htmd) to give the corresponding monomer, (6Clppdz)2Ir(pyzc), (6Clppdz)2Ir(pic), (6Clppdz)2Ir(acac), (6Clppdz)2Ir(tmd), (MCOMppdz)2Ir(acac), and (MCOMppdz)2Ir(tmd), respectively. The complexes show bright orange to red luminescence at room temperature and the emission wavelenghts are affected by the ancillary ligands as well as cyclometalating ligands (593-664 nm).
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
Sang Jin Lee, Jae Sung Lee, Kwang-Jin Hwang, Young Kwan Kim, Young Sik Kim, Noh Gill Park, Eun Ju Shin, Seung Hee Lee,