Article ID Journal Published Year Pages File Type
10731856 Radiation Physics and Chemistry 2005 8 Pages PDF
Abstract
The decomposition reactions of chloroethylenes in air were studied for electron beams and 60Co γ-rays at different dose rates using irradiation vessels having different S/V ratios. The chain termination of their decomposition reactions involves the bimolecular reactions of alkylperoxy radicals (RO2
- ) for high dose-rate irradiations, while it involves the deposition of RO2
- on the wall of the irradiation vessel beside this bimolecular reaction for low dose-rate irradiations, and/or irradiations using vessels having larger inner surface area to volume ratio.
Related Topics
Physical Sciences and Engineering Physics and Astronomy Radiation
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