Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10848153 | Steroids | 2005 | 5 Pages |
Abstract
The stereochemistry of the addition of methylmagnesium bromide to a steroidal 4,5-epoxy-3-ketone has been shown to be determined by the stereochemistry of the epoxide. The epoxidation to the corresponding 3-alkyl-3-hydroxy-4-enes by per-acid was determined by the stereochemistry of the allylic alcohol.
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Authors
Cavit Uyanik, Aslihan Malay, Azra S. Ayna, James R. Hanson, Peter B. Hitchcock,