Determination of inorganic phosphate by electroanalytical methods: A review

Determination of inorganic phosphate is of very high importance in environmental and health care applications. Hence knowledge of suitable analytical techniques available for phosphate sensing for different applications becomes essential. Electrochemical methods for determining inorganic phosphate have several advantages over other common techniques, including detection selectivity, stability and relative environmental insensitivity of electroactive labels. The different electrochemical sensing strategies adopted for the determination of phosphate using selective ionophores are discussed in this review. The various sensing strategies are classified based on the electrochemical detection techniques used viz., potentiometry, voltammetry, amperometry, unconventional electrochemical methods etc., The enzymatic sensing of phosphate coupled with electrochemical detection is also included. Various electroanalytical methods available in the literature are assessed for their merits in terms of selectivity, simplicity, miniaturisation, adaptability and suitability for field measurements.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Advantages of electrochemical sensing of phosphate. ► Classification of electrochemical methods of sensing. ► Ionophores for potentiometric sensing of phosphate. ► Supramolecular based sensing of phosphate: voltammetry and amperometry. ► Unconventional and indirect methods of sensing phosphate.