Article ID Journal Published Year Pages File Type
1230418 Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2016 7 Pages PDF
Abstract

Highlight•A far-red emitting probe for H2S has been developed based on indole-BODIPY platform.•The probe responds to H2S (t1/2 = 2.5 min) rapidly with high sensitivity and selectivity.•The detection limit is as low as 0.02 μM for H2S.

A novel fluorescent probe for H2S was developed based on a far-red emitting indole-BODIPY, which was decorated with morpholine and 2,4-dinitrobenzenesulfonyl (DNBS) group. This probe showed rapid response (t1/2 = 3 min), high selectivity and sensitivity for H2S with significant colorimetric and fluorescence OFF–ON signals, which was triggered by cleavage of 2,4-dinitrobenzenesulfonyl group. This probe could quantitatively detect the concentrations of H2S ranging from 0 to 60 μM, and the detection of limit was found to be as low as 26 nM. Cell imaging results indicated that the probe could detect and visualize H2S in the living cells.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
Authors
, , , , , , ,