Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1270617 | International Journal of Hydrogen Energy | 2014 | 9 Pages |
•A novel series of Au/HTiNbO5 nanosheets photocatalyst was developed.•The 2D HTiNbO5 nanosheets prepared successfully by exfoliation mehold.•Well-dispersed ultra-fine gold nanoparticles are loaded on HTiNbO5 nanosheets.•The 2D Au/HTiNbO5 nanosheets showed a superior photocatalytic activity.
The layered potassium titanium niobate, KTiNbO5, is known as a photocatalyst for hydrogen production from water splitting under UV light. Here we show that titanium niobate nanosheets with a slit like framework can be obtained by exfoliation of KTiNbO5 followed by proton exchange. Gold nanoparticles were deposited on the titanium niobate nanosheets using deposition-precipitation (DP), photo-deposition (PD) and impregnation (IMP) method in order to improve photocatalytic hydrogen production from water splitting.These catalysts were characterized by powder X-ray diffraction patterns (XRD), inductively coupled plasma mass spectrometry (ICP-MS), UV–visible spectroscopy (UV–vis), and Transmission Electron Microscopy (TEM). The gold loaded titanium niobate nanosheets prepared by the DP method consisted of a good metal-semiconductor interface which allowed for a much higher efficient electron–hole separation.In this paper, we developed a facile method of preparing titanium niobate nanosheets containing gold nanoparticles. The titanium niobate nanosheets with Au cocatalyst prepared by the DP method showed a uniform dispersion of gold nanoparticles with an average gold particle size of 3 nm and exhibited an ultra-high photocatalytic water splitting activity, which was 56 times higher than that exhibited by the origin KTiNbO5 photocatalyst.
Graphical abstractIn this paper, we developed a facile method of preparing titanium niobate nanosheets containing gold nanoparticles. The titanium niobate nanosheets with Au cocatalyst prepared by the DP method showed a uniform dispersion of gold nanoparticles with an average gold particle size of 3 nm and exhibited a ultra-high photocatalytic water splitting activity, which was 56 times higher than that exhibited by the origin KTiNbO5 photocatalyst.Figure optionsDownload full-size imageDownload as PowerPoint slide