Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1271504 | International Journal of Hydrogen Energy | 2012 | 9 Pages |
Copper oxide (CuO) semiconductor nanoparticles are of interest because of their promising use for electronic and optoelectronic devices, and the size of the CuO particles for these applications is important. In this work, near spherical CuO nanoparticles with aspect ratio of 1.2–1.3 were made by a flame spray pyrolysis (FSP) method. In FPS, flame temperature, residence time, precursor concentration can be used to control particle size. As the precursor concentration increased from 0.5% to 35% w/w, primary particle diameter increased from 7 ± 2 to 20 ± 11 nm. Larger primary particle diameters were observed in the low gas flow system (set B) due to the long residence time in the high temperature zone. For the dependence of temperature on particle diameter, particles grew to similar diameter, i.e. ∼11 nm, in both flame conditions within the hot temperature zone (80% of melting point of CuO) but for particles having longer residence time, i.e. 550 ms in set B, the standard deviation of particle diameter is 45% larger than for particles with 66 ms as residence time in set A. Modeling gave a result for CuO final particle diameter, based on collision/sintering theory with sintering by solid state diffusion, of 6.7 and 9.0 nm for set A and set B, respectively, with surface tension assumed to be 0.5 J/m2.Comparison with the experiment results, 11 ± 4 nm diameter for both flame conditions, indicates the simulations were reasonable.
► We made nearly spherical CuO nanoparticles with aspect ratio of 1.2–1.3 by flame spray pyrolysis. ► We control particle size by controlling the flame temperature, residence time, and precursor concentration. ► As the precursor concentration increased, primary particle diameter increased. ► Use of low gas flow rates led to larger primary particles, a result of longer residence times in the high temperature zone. ► We simulated particle growth using collision/sintering theory, and found good agreement with experimental results.