Magnetic field aligned nanocomposite proton exchange membranes based on sulfonated poly (ether sulfone) and Fe2O3 nanoparticles for direct methanol fuel cell application

Sulfonated poly (ether sulfone) (SP-ES) are prepared and optimized considering the transport properties and physicochemical stability. Afterward, nanocomposite membranes composed of SP-ES containing various loading weights of γ-Fe2O3 nanoparticles are fabricated. Nanoparticles assembled into an aligned form across the membrane by applying magnetic field during solvent casting. The effect of nanoparticles orientation is studied by consideration of the water uptake, membrane ionic conductivity, and activation energy as well as methanol permeability. Aligned membranes have a higher proton conductivity and also lower activation energy for proton migration as well as lower water uptake and methanol permeability. It is also noted that nanocomposite membranes have sufficient thermal stability and high electrochemical performance. Consequently, the anisotropic nanocomposite membranes with oriented nanoparticles demonstrate the ability to have potential application in fuel cells as well as ionic actuators.

► A series of partially sulfonated poly (ether sulfone) (S-PES) were prepared. ► Polyelectrolyte membranes with oriented microstructure have been investigated. ► Effect of orientation of nanoparticles on principal properties was studied. ► These anisotropic polyelectrolyte membranes have potential application in fuel cells.