Article ID Journal Published Year Pages File Type
1273000 International Journal of Hydrogen Energy 2014 6 Pages PDF
Abstract

•High crystalline Cr-MOF with well-defined shape was prepared via modulated synthesis.•High reproducibility can be expected at certain optimized synthesis conditions.•It has good structure-stability in 80 °C H2O and DMF solutions for 5 days.•It has enhanced H2 storage capacity against the reported results.

Modulated synthesis of MIL-101(Cr) in high yield and with good reproducibility using formic acid as a modulator is reported. Higher molar ratio of formic acid/CrCl3 was found to form better shape-defined MIL-101(Cr) crystals with higher surface area, larger pore volume and better hydrogen uptake performance. The highly crystalline MIL-101(Cr), composed of crystals in the size range of 100–150 nm with multifaceted surface, could be obtained in an optimized molar regime of CrCl3·6H2O/H2BDC/100HCOOH/550H2O at 210 °C for 8 h. The MIL-101(Cr) obtained from the modulated synthesis also showed high thermal and moisture stabilities as well as enhanced hydrogen storage capacity, making this material particularly promising for practical hydrogen storage applications.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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