Electrochemical preparation and characterization of C/Ni–NiIr composite electrodes as novel cathode materials for alkaline water electrolysis

The binary NiIr coatings as novel and effective catalysts were electrochemically prepared on a Ni-modified carbon felt electrode (C/Ni–NiIr) in view of their possible application as cathode materials for the alkaline water electrolysis. The surface morphology and chemical composition of the electrodes were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) techniques. Their hydrogen evolution activity was assessed by electrochemical techniques. It was found that, the preparation of NiIr co-deposits on the Ni-modified C substrate enhances the hydrogen evolution activity. The electrodes have wide space, which is an advantage for diffusion of ions and hydrogen bubbles through inner zones and reduction of diffusion resistance. The high hydrogen evolution activity of the C/Ni–NiIr electrode was mainly attributed to the finer surface structure, high surface area and the higher numbers of the catalytically active centers.

Graphical abstractThe binary NiIr coatings as novel, cost-effective and electrocatalytic electrodes were electrochemically prepared on a Ni-modified carbon felt in view of their possible application as cathode materials for the alkaline water electrolysis.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Novel cost effective and electrocatalytic C/Ni–NiIr catalysts were fabricated. ► Ni and Ir metals can be evenly electrodeposited throughout the C substrate. ► The catalysts have spacious space. ► NiIr co-deposit could further enhance the HER activity of the electrode. ► C/Ni–NiIr is a good cathode material to substitute for present costly electrodes.