Structural analysis of metal hydride-based hybrid hydrogen storage systems

Hybrid hydrogen storage systems, which see the adoption of metal hydride materials charged at high pressure, can be a viable method to reach good gravimetric and volumetric capacities under selected conditions, since hydrogen is stored both as element bound to the hydride and as high pressure gas. A general structural model, which can simulate high pressure hybrid storage tanks, has been developed, with the aim of describing the performance of the system under various operating conditions. A baseline case has been simulated, comparing tanks composed of SS316 and IM6 graphite fiber reinforced epoxy composite that contain metal hydride materials that can store weight fractions of bound hydrogen ranging from 2% to 8%. Sensitivity analyses were performed for the baseline studies with the aim of determining the operating conditions that maximize gravimetric and volumetric capacities. Results show that high pressure systems are optimal (in terms of gravimetric and volumetric capacity) for tank materials having low density and a high allowable stress, while a low operating pressure is preferable for high density tank materials, especially when coupled with metal hydrides capable of storing a high weight fraction of bound hydrogen.

► High pressure metal hydride storage system structural model developed. ► Performance (system gravimetric and volumetric capacity) for different wall materials evaluated. ► Sensitivity analyses carried out under different conditions. ► Optimization of the system carried out for different materials and operating conditions.