| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1274769 | International Journal of Hydrogen Energy | 2012 | 8 Pages |
The influence of different Ti doping levels on the hydrogen adsorption characteristics of Ti-SBA-15 materials prepared by direct one-step synthesis was systematically investigated. The results showed that the intensity of titanol (Ti–OH) and bridging hydroxyl (Ti–O(H)–Si) groups increased with increasing Ti doping level, whereas the hydrogen adsorption capacity gradually decreased. Nitrogen physisorption, transmission electron microscopy, and small and wide-angle X-ray diffraction analyses revealed that excessive Ti doping led to the growth of TiO2 nanoparticles on the intrawall of the mesopores, which clogged the micropores. However, at comparatively low Ti doping level, Ti substitution and/or dispersion in the silica framework was activated, the number of micropores increased, and consequently the hydrogen adsorption capacity was substantially enhanced. The results from this study suggested that the hydrogen adsorption characteristics of Ti-SBA-15 materials prepared by the direct synthesis method were affected not only by generated titanol and bridging hydroxyl groups but also by the increased number of micropores.
► Maximum hydrogen adsorption capacity for Ti-SBA-15 with Ti/Si mass ratio of 0.1. ► Increasing Ti doping levels led to the development of Ti–OH and Ti–O(H)–Si groups. ► Specific surface area and micropore volume decreased with increasing Ti doping. ► Ti doping level affects the hydrogen adsorption characteristics of Ti-SBA-15.
