Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1274986 | International Journal of Hydrogen Energy | 2007 | 10 Pages |
The feasibility of using the controlled hydriding combustion synthesis (CHCS) under a high magnetic field to prepare the Mg–La–Ni ternary hydrogen storage alloys was studied. Comparison was made between the conventional hydriding combustion synthesis (HCS) and the CHCS. The influence of a high magnetic field on the physicochemical properties (thermodynamic and kinetic characteristics, hydrogen absorption/desorption (A/D) properties, thermal behavior, phase composition and morphology) of the Mg–La–Ni composite was analyzed and the results suggested that a high magnetic field can change the microstructure and phase compositions, decrease the hydriding/dehydriding (H/D) temperature and the particle size of the composite, and increase the H/D rates. Based on this study, the lower-temperature metal hydrides prepared by CHCS seem to be technically feasible for lab-scale and it could represent a possible and attractive alternative to prepare the hydrogen storage materials.