| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1275744 | International Journal of Hydrogen Energy | 2013 | 8 Pages |
A variety of ionic liquids has been tested for its catalytic effect on the dehydrogenation of ethylene diamine bisborane (EDB). The catalytic activity of ionic liquids, such as 1-butyl-2,3-dimethylimidazolium chloride ([BMMIM]Cl), 1-butyl-2,3-dimethylimidazolium acetate ([BMMIM][OAc]), 1-butyl-3-methylimidazolium acetate ([BMIM][OAc]) and 1-butyl-3-methylimidazolium methylsulfonate ([BMIM][OMs]) is compared and the mixture [BMMIM]Cl/EDB was investigated. This system is able to deliver about 6.5 wt% of hydrogen at 140 °C competing with conventional hydrogen storage pressure tanks. The correlation between polarity of the ILs and hydrogen yield was investigated and the suitability for hydrogen storage systems is evaluated and discussed.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Fast H2-generation from ethylene diamine bisborane (EDB) promoted by ionic liquids. ► Faster generation and higher total hydrogen yield from EDB in presence of IL. ► EDB/IL release H2 within minutes between 100 and 140 °C. ► Systems deliver 6.5 wt% of H2 at 140 °C competing with conventional H2 storage tanks. ► The correlation between the important polarity of ILs and H2 yields was evaluated.
