Article ID Journal Published Year Pages File Type
1276547 International Journal of Hydrogen Energy 2014 9 Pages PDF
Abstract

•NiCr/LSM dual layer coating on SUS 430 is manufactured by plasma spray.•ASR of coated alloy is below 100 mΩ cm2 after 4000 h oxidation in air.•Coated interconnect is applied in real SOFC stack to evaluate its application.•NiCr/LSM dual layer coating can improve SOFC stack performance.

Ni80Cr20/(La0.75Sr0.25)0.95MnO3 dual-layer coating is deposited on SUS 430 alloy by plasma spray for solid oxide fuel cell (SOFC) interconnect application. The phase structure, area specific resistance (ASR), and morphology of the coating are studied. A two-cell stack is also assembled and tested to evaluate coating performance in an actual SOFC stack. The NiCr/LSM coating adheres well to the SUS 430 alloy after oxidation in air at 800 °C for 2800 h. The ASR and its increasing rate of coated alloy are 25 mΩ cm2 and 0.0017 mΩ cm2/h, respectively. In an actual stack test, the maximum output power density of the stack repeating unit increases from 0.32 W cm−2 to 0.45 W cm−2 because of the application of NiCr/LSM coating. The degradation rate of the stack repeating unit with no coating is 4.4%/100 h at a current density of 0.36 A cm−2, whereas the stack repeating unit with NiCr/LSM coating exhibits no degradation. Ni80Cr20/(La0.75Sr0.25)0.95MnO3 dual-layer coating can remarkably improve the thermal stability and electrical performance of metallic interconnects for SOFCs.

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Physical Sciences and Engineering Chemistry Electrochemistry
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