Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1277490 | International Journal of Hydrogen Energy | 2013 | 5 Pages |
Abstract
•This reaction is conducted without solvent.•The apparent kinetics model of the hydrogenation is established.•The hydrogenation reaction on the catalyst surfaces is the rate controlling step.•This reaction follows the first-order kinetics.•The apparent activation energy of this reaction is 30.94 kJ/mol.
The hydrogenation kinetics of N-ethylcarbazole over Ru/γ-Al2O3 was investigated to find the rate of controlling step on the mass transfer-reaction processes. The results showed that the kinetics of reaction was controlled by the hydrogenation reaction on the catalyst surfaces. This reaction followed first-order kinetics with an apparent activation energy of 30.94 kJ/mol. The apparent kinetics model of the hydrogenation was established.
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Authors
Chao Wan, Yue An, Fengqiu Chen, Dangguo Cheng, Fuying Wu, Guohua Xu,