Article ID Journal Published Year Pages File Type
1277711 International Journal of Hydrogen Energy 2013 8 Pages PDF
Abstract

Under mild conditions (near-neutral aqueous solutions, room temperature, and atmospheric pressure), an attractive electrolyte was expanded for splitting water and three novel oxygen-evolution catalysts (Co-Ci, Ni-Ci, Ag-Ci) were generated. The Co-Ci catalyst showed a high oxygen-evolution rate (24.42 μmol h−1), a low oxygen-evolution overpotential (395 mV) and excellent stability. In addition, the non-amorphous Ag-Ci catalyst, different from reported catalyst, was generated. The catalyst has been further characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), and X-ray photoelectron spectroscopy (XPS).

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► An effective and abundant electrolyte is expanded for splitting water. ► There novel Co-Ci, Ni-Ci, Ag-Ci oxygen-evolution catalysts has been generated. ► The Co-Ci catalyst is a potential candidate for water splitting. ► A non-amorphous Ag-Ci film material is generated.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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