| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1278355 | International Journal of Hydrogen Energy | 2012 | 8 Pages |
Cation ordered perovskites have been recognized as advanced cathode materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs). This study focuses on the effects of Sr substitution on crystal characteristics, electrical properties, and electrochemical performance of SmBa1−xSrxCo2O5+δ (x = 0, 0.25, 0.5, 0.75, and 1.0) as an IT-SOFC cathode material. The electrical conductivity improves with increasing Sr content due to the greater amount of electronic holes originated from the increased interstitial oxygen. The area specific resistances (ASRs) of SmBa1−xSrxCo2O5+δ decrease with Sr content up to x = 0.75 and increase abruptly for x = 1. For x = 0.75, the lowest ASR value, 0.138 Ω cm2, and the highest single cell performance, 1.039 W cm−2 at 600 °C, are obtained. These results indicate that SmBa1−xSrxCo2O5+δ is optimized at x = 0.75 in terms of obtaining the best performance for IT-SOFCs.
► SmBa1−xSrxCo2O5+δ (x = 0, 0.25, 0.5, 0.75, and 1.0) are investigated to identify the effect of Sr substitution for Ba. ► Electrical conductivities are measured by a four-terminal DC arrangement. ► The ASR of symmetrical cells for x = 0.75 is the lowest, 0.138 Ω cm2 at 600 °C by the impedance spectroscopy. ► The maximum power density of SmBa0.25Sr0.75Co2O5+δ-GDC|GDC|NiO–GDC single cell is 1.039 W cm−2 at 600 °C.
