Effects of gas diffusion layer structure on the open circuit voltage and hydrogen crossover of polymer electrolyte membrane fuel cells

The clamping pressure of polymer electrolyte membrane fuel cells for vehicle applications should be typically high enough to minimize contact resistance. However, an excessive compression pressure may cause a durability problem. In this study, the effects of gas diffusion layer (GDL) structure on the open circuit voltage (OCV) and hydrogen crossover have been closely examined. Results show that the performances of fuel cells with GDL-1 (a carbon fiber felt substrate with MPL having rough surface) and GDL-3 (a carbon fiber paper substrate with MPL having smooth surface) are higher than that with GDL-2 (a carbon fiber felt substrate with MPL having smooth surface) under low clamping torque conditions, whereas when clamping torque is high, the GDL-1 sample shows the largest decrease in cell performance. Hydrogen crossover for all GDL samples increases with the increase of clamping torque, especially the degree of increase of GDL-1 is much greater than that of the other two GDL samples. The OCV reduction of GDL-1 is much greater than that of GDL-2 and GDL-3. It is concluded that the GDL-3 is better than the other two GDLs in terms of fuel cell durability, because the GDL-3 shows the minimum OCV reduction.

► We examined the effects of gas diffusion layer structure on the open circuit voltage and hydrogen crossover. ► Increasing clamping torque increases hydrogen crossover for all GDL samples. ► The degree of increase of GDL-1 is much greater than that of the other two GDL samples. ► The OCV reduction of GDL-1 is much greater than that of GDL-2 and GDL-3.