Article ID Journal Published Year Pages File Type
1279487 International Journal of Hydrogen Energy 2008 7 Pages PDF
Abstract

Multi-walled carbon nanotubes (MWNTs) have been synthesized by hemical vapour deposition technique using AB3AB3 alloy hydride catalyst and platinum supported MWNT (Pt/MWNT) and platinum–ruthenium supported MWNT (Pt–Ru/MWNT) electrocatalysts have been prepared by chemical reduction method. MWNT and electrocatalysts have been characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM) and energy dispersive X-ray analysis (EDX). The anode and cathode electrodes of direct methanol fuel cells (DMFC) have been fabricated using Pt–Ru/MWNT and 1:1 Pt/MWNT+Pt/CPt/MWNT+Pt/C electrocatalyst, respectively. Performances of DMFC with these electrodes have been studied at different temperatures and the results have been discussed. A maximum power density of 39.3mW/cm2 at a current density of 130mA/cm2 has been obtained, which could be attributed to dispersion and accessibility of MWNT support and Pt–Ru in the electrocatalyst mixture for methanol oxidation reaction.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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