Article ID Journal Published Year Pages File Type
1280908 International Journal of Hydrogen Energy 2010 8 Pages PDF
Abstract

MgH2 is one of the most promising materials for hydrogen storage. However, its rather slow hydrogen absorption and desorption kinetics and high dissociation temperature essentially limit its application in this field. Nevertheless mixing Mg or MgH2 with small amount of transition metals or their oxides remarkably accelerates the hydrogen kinetics. Recently a series of new hydrides Mg7TiHx, Mg6.5NbHx and Mg6VHx of Ca7Ge type structure has been synthesized. The hydrogen desorption properties have been found to be better than for pure MgH2. Here, we report on the results of our theoretical study of the electronic structure of these new hydrides carried out within the framework of the full-potential, self-consistent linearized augmented plane-wave method. We use these results, along with calculations of the heat of formation and relative stability, to discuss the bonding of these materials and their hydrogen-storage properties.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
Authors
, , ,