500 h Continuous aging life test on PBI/H3PO4 high-temperature PEMFC

500 h continuous aging test on high-temperature PEMFC (phosphoric acid-doped PBI system) was conducted, steady-state performance (current density=640mAcm-2) was recorded, polarization curves were tested every 24 h, and electrochemical techniques—cyclic voltametry (CV) and electrochemical impedance spectroscopy (EIS)—were used to study the relationship between electrochemical surface area (ESA), internal resistance (Rin)(Rin) and charge transfer resistance (Rct)(Rct) with time. Our research results showed that after about 100 h activation, the cell performance began to degrade, and the cell voltage degradation rate is about 150μVh-1 at 640mAcm-2. AC impedance measurements showed that there was no obvious membrane degradation for internal resistance remains almost stable. The main reason for performance degradation is the decrease of ESA and the increase of RctRct, which implied that obvious degradation occurs at catalyst.