Steam reforming of methanol over supported Ni and Ni–Sn nanoparticles

•Synthesis and characterization of Ni and NiSn nanoparticles-based catalysts.•Effect of the preparation method in methanol steam reforming.•Influence of Sn in the formation of carbonaceous deposits.

The influence of the synthesis method and Sn addition on Ni/CeO2–MgO–Al2O3 catalyst is correlated to its catalytic behavior in the reaction of methanol steam reforming. The catalysts prepared by impregnation method are compared to samples obtained by deposition of previously obtained nanoparticles by the polyol method. X-ray diffraction (XRD), specific surface area measurements and H2-temperature programmed reduction (TPR) were used to characterize the catalysts. The differences of the structure, phase transformation and reduction behavior are discussed and related to the catalytic performance of the samples as well as the nature of the carbonaceous deposits formed during the reaction.