Article ID Journal Published Year Pages File Type
1281737 International Journal of Hydrogen Energy 2013 8 Pages PDF
Abstract

A very high temperature reactor (VHTR) has been considered for generation of hydrogen by water-splitting through thermochemical processes using process heat. The development of this technology requires understanding of the coupled behavior of VHTR and the hydrogen generation plants and key safety issues during transients. A system level modeling of the coupled VHTR and sulfur-iodine hydrogen generation process is carried out where the thermal and neutronic models of the VHTR and the chemical models of the sulfur-iodine cycle were developed and benchmarked with available experimental data, models and simulation codes. Transient analysis of the possible accidents emanating either from VHTR or hydrogen plants was carried out. The results indicate that on VHTR side the response of the reactor is affected by the temperature feedback and xenon buildup feedback. On the hydrogen plant side the slowest reaction controlled the speed of the overall response of the chemical plant.

► A transient model for the coupled SI cycle hydrogen plant and PBMR is developed. ► The models were supported and validated with simulation codes and available data. ► Load following transient cases such as loss of flow accident were studied. ► The dynamics of coupled systems is impacted by chemical kinetics of SI cycle.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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