Article ID Journal Published Year Pages File Type
1281836 International Journal of Hydrogen Energy 2007 6 Pages PDF
Abstract

Ag and AgNi powders were comparatively tested as anodic catalysts for direct electrochemical oxidation of borohydride. Discharge experiments demonstrated for the first time that both Ag and AgNi electrode can catalyze the electrooxidation of borohydride, delivering a high capacity of >7e>7e oxidation for a borohydride ion. In comparison, AgNi-catalyzed borohydride fuel cells exhibited a higher discharge voltage and capacity, possibly due to a combined action of the electrocatalytic activity of Ni component for borohydride electrooxidation and the depression of borohydride hydrolysis by Ag atoms.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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