Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1282911 | International Journal of Hydrogen Energy | 2010 | 5 Pages |
Abstract
MmMg12-Ni amorphous or nanocrystalline composites (Mm: Ce-rich mischmetal) were prepared through the ball-milling method, and their electrochemical hydrogen storage performance was investigated and compared with that of ball-milled CeMg12-Ni composites. It was found that the ball-milled MmMg12-Ni composites had larger initial discharge capacities and better high rate dischargeability. Analysis of electrochemical impedance spectra (EIS) shows that the reaction resistance and hydrogen diffusion resistance of the ball-milled MmMg12-Ni composites are lower as a result of the decrease in Ce content, and thus can contribute to the larger discharge capacity and better high rate dischargeability. Additionally, the cycle performance of the ball-milled MmMg12-Ni composites is better than those of the ball-milled CeMg12-Ni composites. This may be related to the formation of a Nd oxide or Nd(OH)3 film on surface of the MmMg12 alloys.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Yi Wang, Xin Wang, Chang Ming Li,