Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1283542 | International Journal of Hydrogen Energy | 2008 | 8 Pages |
Abstract
The effects of temperature and the concentrations of NaBH4, NaBO2 and NaOH on the rate of NaBH4 hydrolysis over carbon-supported ruthenium catalyst were investigated using isothermal rate data extracted from non-isothermal reactions. It was shown that the hydrolysis was a zero-order reaction with respect to the concentration of NaBH4 and the reaction rate decreased with the increase in OH− concentration. A rate expression was then derived to correlate the hydrolysis rate with the temperature and NaOH concentration.
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Authors
Y. Shang, R. Chen, G. Jiang,