| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1303162 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•Tris-β-diketonate Zn2 +-Eu3 +-complex•PMMA-supported grafting-type metallopolymer•High color-purity red-light
Through the copolymerization of a complex monomer [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2; H2L = N,N′-bis(salicylidene)cyclohexane-1.2-diamine; 4-vinyl-Py = 4-vinyl-pyridine and HTTA = 2-thenoyltrifluoroacetonate) with MMA (methyl methacrylate), the first example of PMMA-supported and highly luminous (ФEuL = 63.1%) color-purity red-light metallopolymer poly(MMA-co-2) based on a tris-β-diketonate Zn2 +-Eu3 +-complex is obtained.
Graphical abstractThrough the grafting of a tris-β-diketonate Zn2 +-Eu3 +-complex [Zn(L)(4-vinyl-Py)Eu(TTA)3] (2) in PMMA, the obtained metallopolymers poly(MMA-co-2) exhibit significantly improved physical properties including highly luminous Eu3 +-based color-purity red emissions (ФEuL = 63.1%).Figure optionsDownload full-size imageDownload as PowerPoint slide
