| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1326884 | Journal of Organometallic Chemistry | 2008 | 4 Pages |
Abstract
Cationic Ir complex ([Ir(cod)2]BF4 + BINAP) catalyzed the addition of ortho-C–H bonds in aryl ketones to alkynes, which gave alkenylated products in good to high yield. Styrene derivatives were good substrates, and the enantioselective addition to norbornene was also described.
Graphical abstractCationic Ir–bidentate phosphine complex ([Ir(cod)2]BF4 + BINAP) catalyzed the addition of ortho-C–H bonds in aryl ketones to alkynes and alkenes, which gave alkenylated products in good to high yield.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Kyoji Tsuchikama, Mitsugu Kasagawa, Yu-Ki Hashimoto, Kohei Endo, Takanori Shibata,