| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334273 | Polyhedron | 2016 | 5 Pages |
Abstract
A new dodecanuclear cluster [CoII9CoIII3(MeOsalox)6(OAc)15(H2O)6]·2MeCN·2H2O (1) (H2MeOsalox = 3-methyloxysalicylaldoxime) was synthesized under solvothermal conditions and characterized by IR, elemental analyses (EA), single-crystal X-ray diffraction and powder XRD. Magnetic investigations reveal that complex 1 exhibits antiferromagnetic interactions between the cobalt centers.
Graphical abstractOne mixed-valence cobalt(II/III) dodecanuclear cluster bridged by doubly deprotonated o-vanillin oxime and acetate anions has been assembled. Antiferromagnetic interactions between the cobalt ions are observed.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yu Li, Yaru Qin, Yong Wang, Wei Liu, Yahong Li,