Article ID Journal Published Year Pages File Type
1334321 Polyhedron 2016 7 Pages PDF
Abstract

Eight new heteroleptic ruthenium(II) complexes of 2,2′:6′,2″-terpyridine derivatives are reported and characterized by multinuclear NMR and electrospray mass spectrometry. Complexes featuring pendant aryl bromide or pyridyl groups in the 4′ position of terpyridine are suitable for palladium(0) coupling reactions to form large metallo-supramolecular ligands. Aryl boronic ester derivatives were found to be unstable with respect to hydroxylation.

Graphical abstractEight new heteroleptic Ru(II) complexes of 2,2′:6′,2″-terpyridine which could act as supramolecular building blocks are reported and characterized by NMR and MS.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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