Article ID Journal Published Year Pages File Type
1334342 Polyhedron 2015 9 Pages PDF
Abstract
1,2,4-Oxadiazoline Pt(II) complexes can be synthesized via [3+2] cycloaddition between organonitrile complexes and pyrroline N-oxide. Thermal heating of oxadiazolines affords the derived ketoimines. DFT calculations show that the Pt(II)-catalysed cycloaddition is spontaneous and exergonic. Moreover, the molecular structure, spectroscopic and electronic properties of oxadiazoline Pt complex were predicted.96
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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