| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334550 | Polyhedron | 2013 | 7 Pages |
Abstract
The complex (dippe)Pt(NBE)2 (NBE = norbornene) reacts with thioethers RSR′ upon heating to give C–S oxidative addition products (RSR′ = Ph2S, PhSMe, PhSallyl, MeSallyl, PhSvinyl, PhCH2SMe, PhSCF3, and dithiane). Continued heating leads to disproportionation and formation of R′2 and (dippe)Pt(SR)2 in several cases.
Graphical abstractThe complex (dippe)Pt(NBE)2 (NBE = norbornene) reacts with thioethers RSR′ upon heating to give C–S oxidative addition products (dippe)Pt(SR)(R′).Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sabuj Kundu, Benjamin E.R. Snyder, Aaron P. Walsh, William W. Brennessel, William D. Jones,