| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334580 | Polyhedron | 2013 | 6 Pages |
Abstract
The coordination capability of the pendant-arm macrocyclic ligands L1 and L2 towards nitrate and perchlorate Cd(II) salts, has been investigated. The X ray crystal structure of [CdL1(CH3CN)](ClO4)2·CH3CN shows a mononuclear endomacrocyclic structure with the metal ion coordinated, in a distorted pentagonal bipyramid geometry. The complex [CdL2](ClO4)2 is also mononuclear, but the cadmium ion is in an distorted trigonal prism environment coordinated by the six nitrogen donor atoms from the ligand.
Related Topics
Physical Sciences and Engineering
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Authors
Montserrat López-Deber, Anxela Aldrey, Goretti Castro-Justo, Mª del Carmen Fernández-Fernández, Verónica GarcÃa-González, Rufina Bastida, Alejandro MacÃas, Paulo Pérez-Lourido, Laura Valencia,