A rare polymeric azido-bridged copper(II) chain with a pentameric repeating unit: Synthesis, structure and magnetic properties

The novel polymeric chain copper(II) complex [Cu4(μ-Mesalpn)2(μ1,1,1-N3)2(μ1,1-N3)2Cu]n (1) was prepared by the reaction of Cu(NO3)2·3H2O with Mesalpn in the presence of an excess of NaN3. A single-crystal X-ray diffraction study showed an unusual 1D polymeric chain based on pentanuclear Cu5 units with both μ1,1,1-N3 and μ1,1-N3 bridges, and with three independent Cu(II) ions presenting three different coordination numbers (4, 5 and 6). The magnetic susceptibility data show the presence of dominant anti-ferromagnetic interactions.

Graphical abstractThe single-crystal X-ray diffraction study of the novel polymeric chain copper(II) complex [Cu4(μ-Mesalpn)2(μ1,1,1-N3)2(μ1,1-N3)2Cu]n (1) shows an unusual 1D polymeric chain based on pentanuclear Cu5 units, with both μ1,1,1-N3 and μ1,1-N3 bridges and with three independent Cu(II) ions presenting three different coordination numbers. The magnetic susceptibility data show the presence of dominant anti-ferromagnetic interactions.Figure optionsDownload full-size imageDownload as PowerPoint slide