| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334645 | Polyhedron | 2013 | 9 Pages |
Abstract
⺠Ru(II)-/Os(II)-diiodide-carbonyl complexes of 1-alkyl-2-(arylazo)imidazoles are reported. ⺠Their structures have been established by X-ray diffraction measurements. ⺠Cyclic voltammetry shows metal oxidation and reduction of the chelated azoimine function. ⺠The complexes show catalytic activity for the oxidation of alcohols to aldehydes/ketones by NMO. ⺠DFT calculations of the optimized structures explain the origin of the spectra and redox properties.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shyamal Kumar Sarkar, Mahendra Sekhar Jana, Tapan Kumar Mondal, Chittaranjan Sinha,