| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334786 | Polyhedron | 2012 | 6 Pages |
Abstract
The investigation reports the synthesis of four new stibocanes substituted with cyclic dithiophosphate ligands O(CH2CH2S)2SbS2P(OCH2)2CEt2, O(CH2CH2S)2SbS2P(OCH2)2C(Me)Pr, S(CH2CH2S)2SbS2P(OCH2)2CEt2 and S(CH2CH2S)2SbS2P(OCH2)2C(Me)Pr. The single-crystal structure of two of the compounds were determined and exhibit different types of secondary bonds. The eight membered ring present a boat-chair conformation, while the 1,3,2 dioxaphosphinane ring has the chair conformation, with the stibocane on the axial position.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Patricia GarcÃa y GarcÃa, Patricia MartÃnez-Salas, Simón Hernández-Ortega, Perla Román-Bravo, Marcela López-Cardoso, MarÃa del Carmen Pérez-Redondo, Gabriela Vargas-Pineda, Ave MarÃa Cotero-Villegas, Raymundo Cea-Olivares,