Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1334791 | Polyhedron | 2012 | 9 Pages |
Abstract
⺠Calculated MoE bond distances are significantly short. ⺠Significant electronic charge transferred in the direction [X(PMe3)4Mo]â â [E(Mes)]+. ⺠The MoE bond strength vary as E = Si > Ge > Sn > Pb and X = F > Cl > Br > I. ⺠The Mo â E Ï-donation is much smaller than the Mo â E Ï-back donation. ⺠The out-of-plane Ï-bonding is greater than the in-plane Ï-bonding.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Krishna K. Pandey, Pankaj Patidar,