| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1334822 | Polyhedron | 2011 | 6 Pages |
Two novel heterobimetallic coordination polymers with Hg(SCN)42− as a linker have been synthesized and characterised by means of IR, EPR, magnetic measurements and single crystal X-ray. The compounds [Mn(bpzm)Hg(SCN)4]n (1) and [Mn(bdmpzm)2Hg(SCN)4]n (2) form supramolecular framework structures. The compound 1 creates a three-dimensional coordination polymer and compound 2 has one-dimensional chain structure extending along the crystallographic direction [1 0 0]. Variable-temperature magnetic susceptibility measurements show very weak antiferromagnetic interactions between the paramagnetic Mn(II) centres of structures 1 and 2.
Graphical abstractTwo novel heterobimetallic coordination polymers with Hg(SCN)42− as a linker have been synthesised and characterised by means of IR, EPR, magnetic measurements and single crystal X-ray. The compounds [Mn(bpzm)Hg(SCN)4]n (1) and [Mn(bdmpzm)2Hg(SCN)4]n (2) form polymeric coordination structures. The compound 1 creates a three-dimensional coordination polymer and compound 2 has one-dimensional chain structure extending along the crystallographic direction [1 0 0]. Variable-temperature magnetic susceptibility measurements show very weak antiferromagnetic interactions between the paramagnetic Mn(II) centers of structures 1 and 2.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Two Mn/Hg coordination polymers with Hg(SCN)42− as a linker were obtained. ► [Mn(bpzm)Hg(SCN)4]n and [Mn(bdmpzm)2Hg(SCN)4]n form coordination polymer structures. ► The first complex creates a three-dimensional structure. ► The second one has one-dimensional chain structure extending along [1 0 0] direction. ► Magnetic measurements confirms very weak antiferromagnetic interactions.
