Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1334927 | Polyhedron | 2010 | 7 Pages |
Abstract
Vanadium(V) complexes with glycinehydroxamic acid and three α-aminohydroxamic acids were analyzed using potentiometry and spectroscopy. Formation constants were calculated and structures proposed based on 51V NMR results. VO2L has a distorted trigonal bipyramidal structure and VO2H2L2+ an octahedral one. Both are formed in neutral medium. Only the hydroxamate coordinates to VO2+ .
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
C.T. Miranda, S. Carvalho, R.T. Yamaki, E.B. Paniago, R.H.U. Borges, V.M. De Bellis,