Article ID Journal Published Year Pages File Type
1335004 Polyhedron 2016 6 Pages PDF
Abstract

The first examples of halogen and hydrogen bonding anion receptors containing the redox-active dicationic diquat motif and their anion recognition and electrochemical sensing properties are described. The acyclic receptors demonstrated strong binding affinities for halide anions in competitive solvents, with the most potent anion binding behaviour observed for the halogen bonding analogue. The redox-active diquat group is shown to be an effective electrochemical sensing probe, undergoing significant cathodic perturbations of the diquat2+/diquat+ redox couple upon the addition of halides.

Graphical abstractThe first examples of halogen and hydrogen bonding anion receptors containing the redox-active diquat motif, and their anion recognition and electrochemical sensing properties are described. The halogen bonding host displayed the strongest halide binding affinities in competitive solvents, and the redox-active diquat group is shown to be an effective electrochemical sensing probe for halides.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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