| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1335137 | Polyhedron | 2016 | 9 Pages |
Abstract
The relationship between thermal and photochemical pathways for a 10-vertex metalladecaborane complex has been investigated. The reaction types observed included cage isomerization and nido-6 to hypercloso-metallaborane conversion. UV photochemical irradiation resulted in the formation of the hypercloso-[Mn(CO3)B9H9][NMe4] structure while the thermal reaction produced an isomerization to form the nido-5-[Mn(CO)3B9H13][NMe4] complex.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]](/preview/png/1335137.png "First Page Preview: Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]")
Authors
Pei Ma, Ralf Littger, Tiffany M. Smith Pellizzeri, Jon Zubieta, James T. Spencer,