Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1335472 | Polyhedron | 2014 | 5 Pages |
Abstract
A novel rhenium(IV)-rhenium(V) compound of formula NBu4[ReO2(py)4][ReBr6] (1) (NBu4Â =Â tetra-n-butylammonium cation) was prepared, by reacting [ReBr6]2â and pyridine (py) in acetonitrile, and its crystal structure solved by X-ray diffraction. Compound 1 is the first reported salt of the trans-[ReO2(py)4)]+ cation in where a paramagnetic and highly anisotropic metal ion acts as anion.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
José MartÃnez-Lillo,