Article ID Journal Published Year Pages File Type
1335472 Polyhedron 2014 5 Pages PDF
Abstract
A novel rhenium(IV)-rhenium(V) compound of formula NBu4[ReO2(py)4][ReBr6] (1) (NBu4 = tetra-n-butylammonium cation) was prepared, by reacting [ReBr6]2− and pyridine (py) in acetonitrile, and its crystal structure solved by X-ray diffraction. Compound 1 is the first reported salt of the trans-[ReO2(py)4)]+ cation in where a paramagnetic and highly anisotropic metal ion acts as anion.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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