| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1335518 | Polyhedron | 2007 | 5 Pages |
The chelation of 3-hydroxy-, 5-hydroxy- and 5,7-dihydroxychromone with Al3+ was studied spectrophotometrically. Both the molar ratio method and method of continuous variation (Job’s method) were used to determine the composition of the complexes. In all cases, complex formation involved 1:1 aluminum ion to hydroxychromone ratios. For the 5-hydroxy and 5,7-dihydroxy derivatives, this composition agrees with that for the corresponding hydroxyflavone. However, 3-hydroxyflavone (flavonol) forms a 2:1 complex with Al3+ in methanol in contrast to the results for 3-hydroxychromone in this study. The importance of the cinnamoyl mesomeric form for stabilizing the complex between flavonol and Al3+ is invoked to explain this discrepancy.
Graphical abstractThe coordination of 3-hydroxychromone and 5-hydroxychromones with Al3+ in methanol was studied spectrophotometrically. A comparison with the corresponding flavones gives comparable binding for the 5-hydroxy derivatives. However, where the 3-hydroxyflavone binds in a 2:1 ratio, the 3-hydroxychromone forms a 1:1 complex.Figure optionsDownload full-size imageDownload as PowerPoint slide
