| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1335536 | Polyhedron | 2007 | 7 Pages |
Abstract
Destabilization due to d10-d10 repulsion in structurally characterized copper(I) diphosphinoamine (PPh2)2N(R) (RÂ =Â H; dppa, RÂ =Â iPr; dppipa) dimers such as [Cu2(dppa)2(CH3CN)(H2O)(OClO3)]ClO4 (1), is mitigated by charge transfer interaction promoted by unsymmetrical coordination. Cambridge Structural Database studies support the proposition.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Ritu Ahuja, M. Nethaji, A.G. Samuelson,